DMF is hydrolyzed by strong acids and bases, especially at elevated temperatures. With sodium hydroxide, DMF converts to formate and dimethylamine. DMF undergoes decarbonylation near its boiling point to give dimethylamine.
CAS No.: | 68-12-2 |
---|---|
Formula: | C3h7no |
EINECS: | 292419 |
Type: | Pharmaceutical Intermediates |
Appearance: | Liquid |
Quality: | Industrial |
Model NO. | CAS 68-12-2 | Appearance | Colorless Transparent Liquid |
Product name | Dimethyl Formamide | Purity | 99.95% |
Trademark | SunecoChem | HS Code | 2924191000 |
Origin | China | Specification | 190kg*80 drum |
Dimethylformamide is an organic compound with the formula (CH3)2NC(O)H. Commonly abbreviated as DMF (although this initialism is sometimes used for dimethylfuran, or dimethyl fumarate), this colourless liquid is miscible with water and the majority of organic liquids. DMF is a common solvent for chemical reactions. Dimethylformamide is odorless, but technical-grade or degraded samples often have a fishy smell due to impurity of dimethylamine. Dimethylamine degradation impurities can be removed by sparging degraded samples with an inert gas such as argon or by sonicating the samples under reduced pressure. As its name indicates, it is a derivative of formamide, the amide of formic acid. DMF is a polar (hydrophilic) aprotic solvent with a high boiling point. It facilitates reactions that follow polar mechanisms, such as SN2 reactions.
DMF is hydrolyzed by strong acids and bases, especially at elevated temperatures. With sodium hydroxide, DMF converts to formate and dimethylamine. DMF undergoes decarbonylation near its boiling point to give dimethylamine. Distillation is therefore conducted under reduced pressure at lower temperatures.
In one of its main uses in organic synthesis, DMF was a reagent in the Vilsmeier-Haack reaction, which is used to formylate aromatic compounds.The process involves initial conversion of DMF to a chloroiminium ion, [(CH3)2N=CH(Cl)]+, known as a Vilsmeier reagent, which attacks arenes.
Organolithium compounds and Grignard reagents react with DMF to give aldehydes after hydrolysis in a reaction named after Bouveault.
Dimethylformamide forms 1:1 adducts with a variety of Lewis acids such as the soft acid I2, and the hard acid phenol. It is classified as a hard Lewis base and its ECW model base parameters are EB= 2.19 and CB= 1.31.[17] Its relative donor strength toward a series of acids, versus other Lewis bases, can be illustrated by C-B plots.
1. Used as good solvents on a variety of polymers such as polyethylene, polyvinyl chloride, pan, polyamide, etc. It can be used for acrylic fiber and other synthetic fibers of wet spinning, polyurethane synthesis;
2. Used in the plastic film;
3. Used for catalysts for chemical reactions;
4. Used as a gas absorber for separation and purification of gases in petrochemical industry.
5. Used to remove paint; it can also dissolve some of the low solubility of the pigment, so that the characteristics of dyes with dyes;
6. Used in pesticide industry. It can be used for synthesis of iodine amine pyrimidine, doxycycline, cortisone, vitamin B6,antitumor ammonia acid, furosemide fluorouracil, bile dimension he, etc.
Specification:
ITEM | SPECIFICATION | RESULTS |
Pt-Co chrominance | ≤10 | 5 |
Dimethylamine ppm | ≤15 | 1 |
Formic acid ppm | ≤25 | 2 |
PH: 25°C 20%Aqueous solution | 6.5-8.0 | 7.0 |
Electric Conductivity: 25°C 20%Aqueous solution, us | ≤10 | 0.14 |
Moisture ppm | ≤500 | 106 |
Fe ppm | ≤0.05 | 0.005 |
Methanel ppm | ≤20 | 2 |
Heavy compoment (dimethyl Acetamide) ppm | ≤500 | 39 |
DMF % | ≥99.9 | 99.95 |
1 Q:Are you manufacturer?
A: Yes, We are the largest manufacture on Methylene Chloride, Chloroform and Aniline oil. And ready stock on cyclohexanone, Dimethyl Formamide, Propylene Glycol, Ethylene Glycol, Dimethyl Carbonate, Thiourea, Polyol, TDI, IPA, Ethanol etc.
2 Q: How can you guarantee your quality?
A: Our factory owns mature production line under EPR quality system. We can guarantee the stability and qualification of the raw materials. And we also have SOP loading system to ensure the safety and timely transportation.
3 Q: Can I get some samples?
A: Yes, we can supply samples free of charge, the courier shipping cost will be prepaid by customers.
4 Q: How to confirm the Product Quality before placing orders?
A : You can get free samples from us or taking our previous SGS Reports as reference or arrange SGS before loading.
5 Q: What is your MOQ?
A: Our MOQ is 20'FCL for each product.
6 Q: What kind of package do you have?
A: We have many different packages to meet needs of our customers,like Iron drums,plastic drums, IBC drums, Flexitank, ISO TANK and bags etc.
7 Q :Which kind of payment terms do you accept?
A: TT, LC at sight/ LC 90/120days payment terms are acceptable.
8 Q:Can you give me a discount price?
A: Yes. It depends on your order qty.
9 Q: How about your delivery? How long is your delivery time?
A: Prompt and reliable delivery by professional shipping lines.
Generally it takes 14 days after deposit or original LC.
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Suneco Chem, the name that you can trust. As a vital professional chemical manufacturer in China, we warmly welcome your visit to our factory and talk business face to face! We are at your disposal all the time.